scarlet and violet destined rivals rare cards & including Trainer’s Pokémon and Team Rocket There are 62 Secret Rares

"In the sleepy town of Arkham, Massachusetts, a small band of intrepid investigators seeks to uncover the nature of a sinister menace that threatens humanity

Archeops has appeared across various Pokmon titles, maintaining its presence in the franchise through games like Pokmon Sun and Moon, where it can be transferred via the Pokmon Bank, and Pokmon Sword and Shield, thanks to the Isle of Armor expansion, showcasing its enduring appeal

N 101/101 from Noble Victories (November 2011) is the first full art Trainer card

You could also argue the first ones would then be from Double Crisis, but Id argue those are just regular arts, albeit on the same level of cool art as CHRs